The Bloch sphere represents state with the following probability amplitudes:
$$|\psi\rangle = \cos(\theta/2)\ |0\rangle +e^{i\phi} \sin(\theta/2)\ |1 \rangle, $$
where $\theta$ and $\phi$ are the angles on the Bloch sphere. Each point on the sphere represents a different state. As mentioned by other answers these $\cos(\theta/2) $ and $e^{i\phi} \sin(\theta/2) $ are not probabilities of the state being in the state $0$ or $1$, rather they represents the probability amplitudes. To get a probability form a probability amplitude, we square the probability amplitudes. That is, $\cos^2(\theta/2) $ and $\sin^2(\theta/2) $ are the probabilities, and you see they add up to $1$.
You also notice that the angle $\phi$ does not show up in the expressions for probabilities. Does this mean that we can just ignore $\phi$ all together? No. If we could then indeed we wouldn't need a 2-dimensional sphere to represents the states.
The reason we cannot ignore the angle $\phi$ from our considerations is because of
the superposition principle of quantum mechanics. Suppose we have,
$$|\psi_1\rangle = \frac{1}{\sqrt{2}}( |0\rangle + |1 \rangle), \ \ \ \ \ \ \ \ \ |\psi_2\rangle = \frac{1}{\sqrt{2}}( |0\rangle +e^{i\phi} \ |1 \rangle.$$
Then the superposition principle tells us that we can make a third state out of their superposition,
$$|\psi_3\rangle = N(|\psi_1\rangle + |\psi_2\rangle) = \sqrt{\frac{2}{3+\cos(\phi)}}\left(|0\rangle + \frac{1+e^{i\phi}}{2} |1\rangle \right) ,$$
where $N$ is some normalization factor written down explicitly in the second equality. Anyway, the point here is now $\phi$ is very important. For example the probability of the state $|\psi_3 \rangle$ being in the $|1\rangle$ state is, $$P(1) = \frac{1+\cos(\phi)}{3+\cos(\phi)}$$
which very much depends on $\phi$. In fact this probability ranges from $0.5$ when $\phi = 0$ to $0$ when $\phi = \pi$.