Fix a finite number of states $\sigma_k$, and consider a channel of the form $$\Phi(X)=\sum_k c_{k}(X)\sigma_k.$$
For $\Phi$ to be linear and trace-preserving we must have: $$c_k(X+X') = c_k(X) + c_k(X'), \qquad \sum_k c_k(X)=1.$$ In other words, the coefficients must be linear functionals $c_k\in\mathrm{Lin}(\mathcal X)^*$ for all $k$.
Does this imply that there must be some positive operators $F_k\ge0$ such that $c_k(X)=\operatorname{Tr}(F_k X)$ for all $k$ (which in turn would imply $\sum_k F_k=I$ and thus that $\{F_k\}_k$ is a POVM)? What's a good way to show this?