One way to achieve this is the following way.
Initialise 1 qubit in the $|0\rangle$-state and rotate along the $Y$-axis to
\begin{equation}
\frac{1}{2}|0\rangle+\frac{\sqrt{3}}{2}|1\rangle.
\end{equation}
Append two qubits in the $|0\rangle$-state, and apply a multi-CNOT gate between the 3 qubits: the control is the first qubit in the superposition state, the targets are the other 2 fresh qubits.This gives
\begin{equation}
\frac{1}{2}|000\rangle+\frac{\sqrt{3}}{2}|111\rangle.
\end{equation}
Apply an $X$-rotation to the 2nd qubit and you will find
\begin{equation}
\frac{1}{2}|010\rangle+\frac{\sqrt{3}}{2}|101\rangle.
\end{equation}