Too long for a comment, partially an answer, but the question may need to be updated in response to this.
For $ n$ qubits, we expect the entanglement entropy to be upper bounded by $\log n$, so $\log n$ qubits, we expect the entanglement entropy to be upper bounded by $\log \log n$. Assuming OP intended that to be the question, we want to find the upper bound of $r+\log\log n$.
Let's try to find a counterexample. We can choose each state to have the same entanglement entropy by writing
$$|\psi\rangle\propto |aa\rangle+|bb\rangle$$ and $$|\phi\rangle\propto |cd\rangle+|dc\rangle.$$ With this notation I am implying that $|a\rangle$, $|b\rangle$, etc. are multiqubit states. I'll choose something separable like $|a\rangle=|0\rangle^{\otimes n/2}$, $|b\rangle=|1\rangle^{\otimes n/2}$, $|c\rangle=|0\rangle^{\otimes m/2}$, $|d\rangle=|1\rangle^{\otimes m/2}$. We have entanglement entropies $r=\log 2$ and $\log 2$, regardless of the relative sizes of $n$ and $m$.
Putting these systems together and choosing another bipartition (middle two vs outside two) yields
$$|\Psi\rangle\propto |ac\rangle\otimes |ad\rangle+|ad\rangle\otimes |ac\rangle+|bc\rangle\otimes |bd\rangle+|bd\rangle\otimes |bc\rangle.$$ Each of the terms is orthogonal to each other in my construction (the set $\{|ac\rangle,|ad\rangle,|bc\rangle,|bd\rangle\}$ is orthonormal for the first subsystem, similarly for the second) and so the entanglement entropy is $-\frac{1}{4}\sum_{i=1}^4 \log\frac{1}{4}=\log 4=r+\log 2$.
So if we choose $n=4$, $m=\log n=2$ in base 2, then the proposal is that the entanglement entropy is upper bounded by $r+\log m=\log 4$. OP's proposal holds, but the commenter's proposal of $\max(r,\log\log n)$ (with my edits...) is violated.