The answer to the question is affirmative. Here is an example of a single-parameter two-qubit circuit $U(\theta)$ that allows to prepare all four computational basis states starting from the fiducial state $|00\rangle$:

Specifically, the parameter values to obtain each computational basis state (up to a negligible global phase factor) are the following:
$U(0) |00\rangle = |00\rangle$.
$U(\frac{\pi}{2}) |00\rangle = |01\rangle$.
$U(\pi) |00\rangle = |10\rangle$.
$U(\frac{3\pi}{2}) |00\rangle = |11\rangle$.
The way I arrived at this circuit goes as follows. Let the parameterized $4 \times 4$ unitary matrix we are seeking, $U(\theta)$, be the time-evolution operator of some two-qubit Hamiltonian $\mathcal{H}$, $U(\theta) = e^{-i \theta \mathcal{H}}$. Assuming a priori the relation between the values of the parameter $\theta$ and the computational basis states that are enumerated above, we want
\begin{equation}
U\left(\frac{\pi}{2}\right) = e^{-i \frac{\pi}{2} \mathcal{H}} = \begin{pmatrix}
0 & 0 & 0 & 1 \\
1 & 0 & 0 & 0 \\
0 & 1 & 0 & 0 \\
0 & 0 & 1 & 0
\end{pmatrix},
\end{equation}
in which case our Hamiltonian is given by
\begin{equation}
\mathcal{H} = \frac{2i}{\pi} \ln \left[ \begin{pmatrix}
0 & 0 & 0 & 1 \\
1 & 0 & 0 & 0 \\
0 & 1 & 0 & 0 \\
0 & 0 & 1 & 0
\end{pmatrix} \right] =
\frac{1}{2} \begin{pmatrix}
-1 & 1 - i & -1 & 1 + i \\
1 + i & -1 & 1 - i & -1 \\
-1 & 1 + i & -1 & 1 - i \\
1 - i & -1 & 1 + i & -1
\end{pmatrix}.
\end{equation}
Now that we have the two-qubit Hamiltonian $\mathcal{H}$, the desired single-parameter two-qubit unitary $U(\theta) = e^{-i \theta \mathcal{H}}$ is unequivocally defined. The only missing step is decomposing such two-qubit circuit in terms of basis gates for an arbitrary value of the parameter $\theta$. There are multiple ways of doing this; I opted for diagonalizing $\mathcal{H}$, as in $\mathcal{H} = V D V^{\dagger}$, which allows to express $U(\theta)$ as $U(\theta) = V e^{-i \theta D} V^{\dagger}$, thus leaving the $\theta$-dependence entirely to the diagonal part, which is easier to decompose.