The mathematical construct of the Quantum process tomography is given in Page 391, 392, Chapter 8, Quantum Computation and Quantum Information by Nielsen and Chuang, as follows
Let a fixed set of operators $\tilde{E}_i$, which form a basis for the set of operators on the state space so that $E_i=\sum_m e_{im}\tilde{E}_m$, then the quantum operation can be represented as, \begin{align} \mathcal{E}(\rho)&=\sum_i E_i\rho E_i^\dagger \tag{8.150}\label{eq0}\\ &=\sum_{m,n}\tilde{E}_m\rho\tilde{E}^\dagger_n \chi_{mn} \tag{8.152}\label{eq2}\\ \end{align} where $\chi_{mn}=\sum_i e_{im}e^*_{in}$ are the entries of a matrix that is positive hermitian since $\chi_{mn}^*=(\sum_i e_{im}e^*_{in})^*=\sum_i e_{in}e^*_{im}=\chi_{nm}$ and $\chi_{mm}=\sum_i e_{im}e^*_{im}=\sum_i |e_{im}|^2\geq 0$.
Let $\rho_j,1\leq j\leq d^2$ be a fixed, linearly independent basis for the space of $d\times d$ matrices,i.e., any $d\times d$ matrix can be written as a unique linear combination of the $\rho_j$ and it is possible to determine $E(\rho_j)$ by state tomography, for each $\rho_j$.
Each $E(\rho_j)$ may be expressed as a linear combination of the basis states, $\mathcal{E}(\rho_j)=\sum_k \lambda_{jk}\rho_k \tag{8.155}\label{eq5}$
And, since $\mathcal{E}(\rho_j)$ is known from the state tomography, $\lambda_jk$ can be determined by standard linear algebraic algorithms. we can also write $\tilde{E}_m\rho_j\tilde{E}_n^\dagger=\sum_k\beta_{jk}^{mn}\rho_k \tag{8.156}\label{eq6}$
where $\beta_{jk}^{mn}$ are complex numbers that can be determined by standard algorithms from linear algebra given the $\tilde{E}_m$ operators and the $\rho_j$ operators.
Combining both obtain, \begin{align} \sum_k\sum_{mn}\chi_{mn}\beta_{jk}^{mn}\rho_k&=\sum_{k}\lambda_{jk}\rho_k\tag{8.157}\label{eq7}\\ \implies \sum_{mn}\beta_{jk}^{mn}\chi_{mn}&=\lambda_{jk} \tag{8.158}\label{eq8}\\ \implies \beta\vec{\chi}&=\vec{\lambda} \tag{8.161}\label{eq61} \end{align} Let $\kappa$ be the generalized inverse such that $\beta\kappa\beta=\beta\Leftrightarrow \beta_{jk}^{mn}=\sum_{st,xy}\beta_{jk}^{st}\kappa_{st}^{xy}\beta_{xy}^{mn}$
We can prove that $\chi$ defined by $\chi_{mn}\equiv\sum_{jk}\kappa_{jk}^{mn}\lambda_{mn}\Leftrightarrow\vec{\chi}=\kappa\vec{\lambda}\tag{8.160}\label{eq60}$ satisfies the equation $\sum_{mn}\beta_{jk}^{mn}\chi_{mn}=\lambda_{jk}\Leftrightarrow\beta\vec{\chi}=\vec{\lambda}$
But now it is stated that,
The difficulty in verifying that $\chi$ defined by \ref{eq0} satisfies \ref{eq8} is that, in general, $\chi$ is not uniquely determined by Equation \ref{eq8}
What is the logic in saying that $\chi$ is not uniquely defined by equation \ref{eq8} ?
In the next step, it says
From the construction that led to Equation \ref{eq2}, we know there exists at least onesolution to Equation \ref{eq61}
How do I make sense of this ?
In deriving equation \ref{eq2} we used the substitution $E_i=\sum_m e_{im}\tilde{E}_m$ into the expression $\mathcal{E}(\rho)=\sum_i E_i\rho E_i^\dagger$.