A state vector on $n$ qubits is a $2^n$ complex number representing a system in a pure state. A density matrix on $n$ qubits is a $2^n$ by $2^n$ matrix representing a system in a mixed state. Mixed states are the more general description of a quantum system, they handle situations, for example, when you have a classical statistical ensemble of pure states. Often, however, you only need to deal with pure states, for example if you have closed system and don't do any measurements on the system.
Different simulators will differ on whether they simulate cases where the system is a pure state and systems where there is a mixed state. Because mixed states are more general, there are places where you have to used mixed state simulation, but, for example for simulating a quantum circuit without the measurement, you really just need the pure state.
Tensor networks are different concept altogether. Tensor networks are different ways to represent the objects like pure states (a $2^n$ vector of complex numbers) or mixed states (a $2^n$ by $2^n$ matrix of complex numbers). Tensor networks can also be used to represent objects besides states (pure or mixed), for example they can be used to represent unitary evolution operators, aka quantum gates.
What are these tensor networks? A tensor is a generalization of a vector or a matrix to an object that is indexed by $r$ different indices (so a vector has one index $v_i$, a matrix has two $m_{i,j}$, and a tensor may have more indices like $t_{i,j,k,l}$). Tensor networks are a set of tensors along with a way to "contract" the tensors. It's easiest to just write a simple example. A tensor network representation of a matrix $m_{i,j}$ might be
$$m_{i,j} = \sum_{k,l} a_{i,k} b_{k,l} c_{l,j}$$
The thing on the left is a matrix, and we are expressing it as a sum (contracting indices) over a product of three tensors. Tensor network methods use this sort of thing to represent states and unitaries and other quantum linear algebraic structures.
When people talk about a pure state simulator, they tend to be refering to a simulator that just keeps the pure state in memory. When people talk about a tensor network simulator, it could be a pure or mixed state simulator, it just refers to the internal representation used for the states.
As for scaling, none of the simulations scale generally polynomially with $n$. Tensor network methods, however, often have some tunable dimension (the dimension of that index that was summed over above) and for constant tunable dimension, the scaling can be polynomial. However, this often only works for simulating some particular states and not all states (so great when this works, not so great when it doesn't).