A qubit in the state $|1\rangle + |0\rangle$, normalized, is time-dependent, right? So it sweeps around the equator of the Bloch sphere at a frequency proportional to the energy gap according to Schrodinger's equation?
With no applied field and energy levels $E_1$ and $E_0$, with $\psi=\begin{bmatrix}a\\b\end{bmatrix}$, you have Schrodinger's equation
$\frac{d}{dt}a=-iE_0/\hbar a$ and $\frac{d}{dt}b=-iE_1/\hbar$ so $\phi=arctan2(b,a)$ is time dependent with frequency $(E_1-E_0)/\hbar$, and that is the angle of rotation about the z axis in the Bloch sphere.
Am I missing something?