In section 8.2.3 of Nielsen and Chuang, they discuss how unitary dynamics of a system and environment arise from quantum operations (i.e. Kraus operators $E_k$ such that $\sum_k E_k^*E_k=I$). Importantly, they mention that
"we are trying to find a model environment giving rise to a dynamics described by the operation elements $\{E_k\}$."
In what follows they let $|e_k\rangle$ be an orthonormal basis for the environment. They then go on to say
"Define an operator $U$ which has the following action on states of the form $|\psi\rangle|e_0\rangle$, $$U|\psi\rangle|e_0\rangle=\sum_k E_k|\psi\rangle|e_k\rangle,\quad\quad\quad\quad\quad (8.37)$$ where $|e_0\rangle$ is just some standard state of the model environment."
Let $\mathcal{H}$ and $\mathcal{K}$ be the Hilbert spaces of the system and environment respectively and suppose we fix the environment $\mathcal{K}$.
My question is whether every unitary on $\mathcal{H}\otimes \mathcal{K}$ has the form of $U$ in equation (8.37)?
I see how defining the action of $U$ in (8.37) leads to these unitary dynamics. This is just the same thing as saying that any isometry on $\mathcal{H}$ extends to a unitary on $\mathcal{H}\otimes \mathcal{K}$. I guess my question is whether the converse is true, does every unitary on the joint system decompose into something of the form in (8.37)? Is there some counterexample, or argument to see that any such unitary has this decomposition?