When pure states $|\psi_1⟩$, $|\psi_2⟩$ and $|\phi_1⟩$, $|\phi_2⟩$ in $\mathcal{H}_A \otimes \mathcal{H}_B$ have identical statistical mixtures $$\frac{1}{2}(|\psi_1⟩⟨\psi_1| + |\psi_2⟩⟨\psi_2|) = \frac{1}{2}(|\phi_1⟩⟨\phi_1| + |\phi_2⟩⟨\phi_2|) ,$$ then we know (by linearity of the partial trace) that the reduced states $\rho_i = \text{tr}_B |\psi_i⟩⟨\psi_i|$ and $\sigma_i = \text{tr}_B |\phi_i⟩⟨\phi_i|$ on the space $\mathcal{H}_A$ also have identical mixtures $\frac{1}{2}(\rho_1 + \rho_2) = \frac{1}{2}(\sigma_1 + \sigma_2)$. My question concerns the converse of this statement.
Let $\rho_1$, $\rho_2$ and $\sigma_1$, $\sigma_2$ be density operators on a finite-dimensional space $\mathcal{H}$ which satisfy $$\rho_1 + \rho_2 = \sigma_1 + \sigma_2 .$$ Do there always exist corresponding purifications $|\psi_1⟩$, $|\psi_2⟩$ and $|\phi_1⟩$, $|\phi_2⟩$ in $\mathcal{H} \otimes \mathcal{P}$ (for some purifying space $\mathcal{P}$) of the $\rho_1$, $\rho_2$ and $\sigma_1$, $\sigma_2$ which satisfy $$|\psi_1⟩⟨\psi_1| + |\psi_2⟩⟨\psi_2| = |\phi_1⟩⟨\phi_1| + |\phi_2⟩⟨\phi_2| ?$$
More generally, I would like to know about when (if at all) identical mixtures of the form $\sum_i p_i \rho_i = \sum_i q_i \sigma_i$ imply the existence of purifications such that $\sum_i p_i |\psi_i⟩⟨\psi_i| = \sum_i q_i |\phi_i⟩⟨\phi_i|$.