If we label the expansion coefficients as $c_{N_1,N_2}(t)$ as suggested in the comments, the correct expression will be
$$c_{N_1,N_2}(t)= \vphantom{a}_a\langle N_1| \vphantom{a}_b\langle N_2|\psi(t)\rangle= \vphantom{a}_a\langle N_1| \vphantom{a}_b\langle N_2|e^{-i H_{NL}t}|N\rangle_a|0\rangle_b.$$
Responding to the comment: some people write their Hilbert spaces in opposite order when using bras, preferring to write this expression as
$$c_{N_1,N_2}(t)= \vphantom{a}_b\langle N_2|\vphantom{a}_a\langle N_1|\psi(t)\rangle= \vphantom{a}_b\langle N_2|\vphantom{a}_a\langle N_1|e^{-i H_{NL}t}|N\rangle_a|0\rangle_b.$$ This does not change the answer, so long as the appropriate subscripts are used to appropriately match the Hilbert spaces.