The quantum conditional entropy $S(A|B)\equiv S(AB)-S(A)$, where $S(AB)=S(\rho_{\rm AB})$ and $S(B)=S(\rho_{\rm B})$ is known to be non-negative for separable states. For entangled states, it is known that the quantum conditional entropy can attain both negative and positive values. Thus, a negative quantum conditional entropy serves as a sufficient, but not necessary, criterion for the quantum state to be entangled. References where this is stated would be https://arxiv.org/pdf/1703.01059.pdf or https://arxiv.org/pdf/quant-ph/9610005.pdf.
While it is easy to find entangled states which yield negative quantum conditional entropies, such as any pure entangled state, I cannot think of/construct an entangled state which yields a positive quantum conditional entropy. Can someone provide an example?