The first answer discusses what the pseudothreshold is and how to find it, but I will try to give a few details on the difference between thresholds and pseudothresholds, since your first question does ask for both definitions.
In quantum error correction (QEC), a logical qubit is encoded in many physical qubits. Given some underlying physical error rate $p$, there will be a corresponding logical error rate $\bar{p}$. If we are smart with our encoding and can make hardware that is "good enough", then ideally $\bar{p} < p$ below some $p_{th}$ for the physical error rate.
When simulating QEC codes, if one type of circuit component (like a single qubit gate) is assumed to fail with some rate $p$, we might obtain a plot like the one below (left). The parameter $L$ refers to the code concatenation; $L=0$ means no QEC, $L=1$ means each logical qubit is encoded with a set of physical qubits, $L=2$ means each of the $L=1$ physical qubits itself is encoded, etc. Notice that there is clean crossover (i.e. all curves intersect the $L=0$ curve at the same point, the threshold), below which using higher levels of concatenation improves the logical error rate of the code with respect to the physical error rate ($\gamma$ is used as the rate symbol here).
But in more complicated models we might allow different circuit components (1-qubit vs. 2-qubit gates, ancilla vs. data wires, etc.) to fail with different error rates, which leads to a more complicated set of curves (right image). Each concatenation curve intersects the $L=0$ curve at a different point, so you cannot just find the threshold of, say, the $L=1$ code and then scale up to higher $L$--you will actually make the code worse, because you only found a pseudothreshold. Instead, you need to simulate many values of $L$ and infer some kind of asymptotic behavior in the curves to get a rough estimate of where it is truly safe to scale up.
In summary, the left image represents the situation where all pseudothresholds are the same and are equal to the true threshold, and the right image represents a more realistic situation where the use of a more complex error model requires us to study the limiting behavior of a family of pseudothresholds.

I took these details and image from this paper.