$\newcommand{\bra}[1]{\left<#1\right|}\newcommand{\ket}[1]{\left|#1\right>}\newcommand{\bk}[2]{\left<#1\middle|#2\right>}\newcommand{\bke}[3]{\left<#1\middle|#2\middle|#3\right>}$ In Quantum Computation and Quantum Information the authors make the following statement "[G]iven any basis states $\ket{a}$ and $\ket{b}$ for a qubit, it is possible to express an arbitrary state as a linear combination $\alpha\ket{a} + \beta\ket{b}$ of those states." They go on to say that if the states are orthonormal, then one can perform a measurement with respect to the $\ket{a}\!, \ket{b}$ basis.
My question is does this imply that any two distinct pure states $\ket{a}$ and $\ket{b}$ form a basis for the Bloch sphere? (I apologize if this might make more sense in reference to a Hilbert space or some other vector space but I haven't gotten to that point in the book yet and have no experience with it otherwise).
It appears that any two distinct pure states are linearly independent, so I would suspect yes, but I do not believe I know enough to prove it.
For example, I attempted to try to transform the state defined by $\ket{\psi} = \frac{\sqrt{2 + \sqrt{2}}}{2}\ket{0} + \frac{\sqrt{2 - \sqrt{2}}}{2}\ket{1}$ into the basis $\{\ket{0}\!, \ \ket{+}\}$ where $\ket{+} = \frac{\ket{0} + \ket{1}}{\sqrt{2}}$. I obtained the following: $$ \begin{align*} \ket{\psi} &= \alpha\ket{0} + \beta\ket{1} = \alpha\ket{0} + \beta(\sqrt{2}\ket{+}-\ket{0}) = (\alpha - \beta)\ket{0} + \sqrt{2}\beta\ket{+}\\ &= \frac{ \sqrt{2+\sqrt{2}} - i\sqrt{2-\sqrt{2}} }{2}\ket{0} + \frac{i\sqrt{2}\sqrt{2 - \sqrt{2}}}{2} \ket{+} \end{align*} $$
This basis is neither orthogonal nor normal, so we would not be able to make a measurement with respect to it, however I believe that this is still a valid way to represent a state.
As the requirement that the basis be orthonormal in order to perform a measurement with respect to it implies that such bases exist, I would be interested in an example of orthogonal but not normal basis. I believe that taking two orthogonal bases (antipodal with respect to the bloch sphere), then scaling them, would be sufficient to realize this type of example.
I would also be interested in an example of a normal but not orthogonal basis, however no simple examples come to mind (it may be that there are no simple examples).